The circular dichroism of 3-alkylthio- and 3-arylthio-cyclohexanones: an analysis of through bonds and dynamic coupling contributions to the optical activity
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 11,p. 1327-1331
- https://doi.org/10.1039/p29820001327
Abstract
The c.d. spectra of a series of 3-alkylthio- and 3-arylthio-cyclohexanones were recorded and interpreted by means of MO calculations and dynamic coupling approximations. From the analysis, the absolute configurations of the compounds were deduced.Keywords
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