OXOVANADIUM (IV) COMPLEXES OF SCHIFF-BASES DERIVED FROM 2-AMINOPYRIDINE AND AROMATIC 2-HYDROXYALDEHYDES
- 1 July 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 16 (1) , 67-73
- https://doi.org/10.1080/00958978708079807
Abstract
Seven new complexes of general formulae [VO(OC6H4X–CR=N–py)2] and [VO(OC10H8CH=N–py)2] have been prepared and characterised by microanalysis, room temperature magnetic moments, conductivity and spectroscopic measurements. Although the complexes are five-coordinate, at least two modes of bonding with the donor atoms are observed, and these depend on electronic effects of the substituents on the phenyl ring.Keywords
This publication has 21 references indexed in Scilit:
- The alternative nitrogenase of Azotobacter chroococcum is a vanadium enzymeNature, 1986
- Nitrogen fixation: A role for vanadium at lastNature, 1986
- Preparation, properties, crystal and molecular structure of uranyl(VI) complexes with a new cyclic schiff base compartmental ligandInorganica Chimica Acta, 1986
- New perspectives on the essential trace elementsPublished by American Chemical Society (ACS) ,1985
- Characterization of oxovanadium(IV) substituted bovine carbonic anhydrase BInorganica Chimica Acta, 1979
- Metabolic patterns of vanadium in the ratBioinorganic Chemistry, 1978
- Stereochemical features of some oxovanadium(IV) complexes of Schiff bases derived from salicylaldehyde derivatives, o-hydroxyphenones and 2,2′-aminoethyl pyridineJournal of Inorganic and Nuclear Chemistry, 1977
- Use of the vanadyl(IV) ion as a new spectroscopic probe of metal binding to proteins. Vanadyl insulinJournal of the American Chemical Society, 1973
- Metal Complexes of Schiff Bases Obtained from Substituted Salicylaldehydes and 2-Aminopyridine DerivativesBulletin of the Chemical Society of Japan, 1969
- ON THE MECHANISM OF THE ENZYMATIC DECARBOXYLATION OF ACETOACETATE1Journal of the American Chemical Society, 1959