Pentachalcogenide dianions in transition-metal complexes: crystal structure of bis-(π-cyclopentadienyl)titanium pentasulphide
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 7,p. 410-411
- https://doi.org/10.1039/c29700000410
Abstract
The anionic pentasulphide chain S5 2– acts as a bidentate ligand to form the “hetero-cyclohexahalcogen”(C5H5)2TiS5: the TiS5 ring fragment has the chair conformation with Ti–S bond lengths of 2·420 and 2·446 Å and S–S bond lengths which range from 2·051–2·059 Å.Keywords
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