A stereoselective synthesis of α-isosparteine
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 654-655
- https://doi.org/10.1039/c39830000654
Abstract
Successive cycloaddition of Δ1-piperidiene 1-oxide to 4H-pyran proceeded regio- and stereo-selectively to afford a 2:1 adduct, catalytic hydrogenation of which gave α-isosparteine in high yield.Keywords
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