KINETICS OF THE ABSTRACTION OF HYDROGEN ATOMS FROM HYDROGEN SULFIDE BY TRIFLUOROMETHYL RADICALS

15 June 1966

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 44 (12) , 1445-1449
https://doi.org/10.1139/v66-213

Abstract

Trifluoromethyl radicals generated from the photolysis of hexafluoroacetone abstract hydrogen atoms from hydrogen sulphide.[Formula: see text]The rate constant of this reaction measured by comparing the rate with that for the recombination of trifluoromethyl radicals (k = 2.3 × 1013 cc mole−1 s−1) is given by,[Formula: see text]

Keywords

RECOMBINATION
HYDROGEN SULFIDE
RATE CONSTANT
ATOMS
HYDROGEN SULPHIDE
RADICALS GENERATED
REACTION MEASURED
ABSTRACT HYDROGEN
HEXAFLUOROACETONE ABSTRACT
CC MOLE

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