On the Construction of the C/D‐Ring Systems of Aphidicolin and Stemodin: a Regio‐ and Stereospecific Synthesis of 17‐Noraphidicolaii‐16 one and 17‐Norstemodan‐16‐one Preliminary Communication
- 3 February 1982
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 65 (1) , 371-376
- https://doi.org/10.1002/hlca.19820650139
Abstract
A very simple regio‐ and stereospecific synthesis of 17‐noraphidicolan‐16‐one and 17‐norstemodan‐16‐one by solvolytic rearrangement of suitable bicyclo[2.2.2]‐‐octenyl methanesulfonate is described.Keywords
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