Base-catalysed rearrangement of β-hydroxyvinylsilanes to allyl silyl ethers
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 165-166
- https://doi.org/10.1039/c39830000165
Abstract
A 1,3-silyl group shift from carbon to oxygen occurs readily when β-hydroxyvinylsilanes are treated with catalytic amounts of sodium hydride in hexamethylphosphoric triamide, thus providing the first demonstration of the rearrangement of silicon from sp2-carbon to oxygen.Keywords
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