Apparent Molar Volumes of Salts and Metals In Liquid Ammonia at 0°
- 15 January 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (2) , 363-367
- https://doi.org/10.1063/1.1732510
Abstract
Apparent molar volumes of some metals and salts in dilute liquid ammonia solutions at 0° have been measured with a direct‐mixing dilatometer. There is little volume change involved in dissociation of diamagnetic metal species, but a large volume decrease results from dissociation of ion‐pairs in salt solutions. Volumes are estimated for single ions and the solvated electron.Keywords
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