A novel tantalum butterfly oxo cluster

Abstract
5-C5Me5)Ta(H)22-CHPMe2)(PMe3) reacts with deoxygenated water in benzene to give the novel tetranuclear butterfly oxo cluster [(η5-C5Me5)Ta]42-O)43-O)24-O)(OH)2 containing doubly, triply, and quadruply bridging oxo ligands, the X-ray crystal structure of which has been determined.

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