REACTIVE LATTICE OXYGEN IN MULTICOMPONENT BISMUTH MOLYBDATE CATALYST FOR OLEFIN OXIDATION
- 5 April 1986
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (4) , 533-536
- https://doi.org/10.1246/cl.1986.533
Abstract
Position of the reactive lattice oxygen in the multicomponent bismuth molybdate catalyst was determined based on the isotope shift in Mo–O stretching vibration by measuring infrared and Raman spectra of the 18O-substituted catalyst with propylene oxidation using 18O2 tracer. It was proven that the oxidation reaction of olefin proceeds in accordance with the “water tank model” proposed by Moro-oka.This publication has 4 references indexed in Scilit:
- Selective oxidation of propene over bismuth molybdate catalysts: The oxidation of propene using 18O labeled oxygen and catalystJournal of Catalysis, 1971
- The mechanism of oxygen atom incorporation into the products of propylene oxidation over bismuth molybdate*1Journal of Catalysis, 1970
- Crystal Structure of the Transition-Metal Molybdates. I. Paramagnetic Alpha-MnMoO4The Journal of Chemical Physics, 1965
- The crystal structure of cobalt molybdate CoMoO4Acta Crystallographica, 1965