Synthesis and Characterization of Directly Linked Salen–Porphyrin System with Constrained Geometries
- 1 January 1991
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 64 (1) , 29-34
- https://doi.org/10.1246/bcsj.64.29
Abstract
Novel heterobinucleating porphyrin complexes, in which porphyrin and salen [N, N′-disalicylidene-ethylenediamine] subunits were directly linked with restricted geometries, were synthesized. These complexes showed a small change in their UV-vis spectra and oxidation potentials, but the fluorescence of porphyrin was effectively quenched by the linked nickel–salen subunit.Keywords
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