Synthesis of allenylketenimines via titanocene vinylidene complexes
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 35-36
- https://doi.org/10.1039/c39920000035
Abstract
The intermolecular addition of in situ generated titanocene vinylidene complexes to alkynes gives titanacyclobutenes which undergo an insertion–rearrangement with tert-butyl isocyanide to afford allenylketenimines in high yield.Keywords
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