Stereoselectivity of ring closure of substituted hex-5-enyl radicals
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 484-485
- https://doi.org/10.1039/c39800000484
Abstract
1,5-Ring closure of 1- or 3-substituted hex-5-enyl radicals affords mainly cis-disubstituted cyclic products, whereas 2- or 4-substituted species give mainly trans-products; the significance of this stereoselectivity is demonstrated in the formation of the norbornane system from acyclic precursors.Keywords
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