Asymmetric induction via co-ordination to Cr(CO)3; nucleophilic attack on acyclic carbenium ions
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1110-1112
- https://doi.org/10.1039/c39800001110
Abstract
Temporary complexation of (S)-(–)-1-phenylethanol by the Cr(CO)3 moiety allows the use of carbenium ions to bring about asymmetric transformations with a high degree of retention of configuration, even in open-chain compounds.Keywords
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