Preparation of Thin Single Crystals of Diacetylene by Pseudo-Homo Epitaxy
- 1 October 1992
- journal article
- Published by IOP Publishing in Japanese Journal of Applied Physics
- Vol. 31 (10B) , L1498
- https://doi.org/10.1143/jjap.31.l1498
Abstract
Thin single-crystal growth of diacetylene monomer between a substrate and a glass plate has been investigated from the molten state. Among five different substrates examined, polydiacetylene single crystal, having the characteristics of pseudo-homo epitaxy, attained the best performance of growth control to give thin single crystals with the size of over one mm2 as well as uniaxial orientation. The crystals were successfully converted into polymer thin single crystals, which were usefull enough for nonlinear optical device fabrication.Keywords
This publication has 10 references indexed in Scilit:
- Single orientation in poly(diacetylene) films for nonlinear optics. Molecular epitaxy of 1,6-bis(9-carbazolyl)-2,4-hexadiyne on organic crystalsMacromolecules, 1991
- Nonlinear optical properties of highly oriented polydiacetylene evaporated filmsApplied Physics Letters, 1989
- Nonlinear optical processes in a polydiacetylene measured with femtosecond duration laser pulsesApplied Physics Letters, 1986
- Growth of large-area thin-film single crystals of poly(diacetylenes)Macromolecules, 1985
- A differential scanning calorimeter study of the crystal forms and polymerization kinetics of 2,4‐hexadiynyl‐1,6‐bis(p‐toluenesulfonate)Journal of Polymer Science: Polymer Physics Edition, 1978
- Optical Nonlinearities in One-Dimensional-Conjugated Polymer CrystalsPhysical Review Letters, 1976
- Solid state polymerization of bis-(p-toluene sulphonate) of 2,4-hexadiyne-1,6-diolJournal of Materials Science, 1975
- Poly-[1,2-bis-(p-tolylsulfonyloxymethylen)-1-buten-3-inylen]Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1974
- Topochemical reactions of monomers with conjugated triple‐bonds. IV. Polymerization of bis‐(p‐toluene sulfonate) of 2.4‐hexadiin‐1.6‐diolDie Makromolekulare Chemie, 1971
- Topochemische Reaktionen von Monomeren mit konjugierten Dreifachbindungen / Tochemical Reactions of Monomers with conjugated triple BondsZeitschrift für Naturforschung B, 1969