Phenyliodonium bis(perfluoroalkane sulphonyl) methide; synthesis and reactions as a precursor of bis(perfluoroalkanesulphonyl) carbene

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Abstract
Photoreaction of the title compound Phl+–C(RFSO2)2 which was synthesised by the reaction of bis(perfluoroalkanesulphonyl) methane with diacetoxyiodobenzene, with alkene, methanol, bromine and benzene gave corresponding addition or insertion products, via the bis(perfluoroalkanesulphonyl) carbene, (RFSO2)2C: intermediate.