The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes
- 1 January 1989
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 42 (11)
- https://doi.org/10.1071/ch9891907
Abstract
The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.Keywords
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