Anion-assisted trans–cis isomerization of palladium(ii) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions
- 2 February 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1572-1574
- https://doi.org/10.1039/b418202b
Abstract
The anion-assisted shift of trans–cis isomerization equilibrium of a palladium(II) complex containing acetanilide functionalities brought about by allosteric hydrogen bonding interactions has been established by UV/Vis, 1H NMR, 31P NMR and ESI-MS studies.Keywords
This publication has 15 references indexed in Scilit:
- First Observation of Alkali Metal Ion Induced Trans–Cis Isomerization of Palladium(II) Phosphane Complexes Containing Crown Ether MoietiesAngewandte Chemie International Edition in English, 2003
- Cis and Trans Isomers of Pt(SiHAr2)2(PR3)2(R = Me, Et) in the Solid State and in SolutionsOrganometallics, 1999
- Uncatalyzed Cis-Trans Isomerization of Bis(pentafluorophenyl)bis(tetrahydrothiophene)palladium(II) Complexes in Chloroform: Evidence for a Dissociative MechanismInorganic Chemistry, 1994
- Anion Binding Sites in Protein StructuresJournal of Molecular Biology, 1993
- Ion-responsive fluorescent compounds. 4. Effect of cation binding on the photophysical properties of a coumarin linked to monoaza- and diaza-crown ethersThe Journal of Physical Chemistry, 1993
- A new reaction pathway for the geometrical isomerization of monoalkyl complexes of platinum(II): kinetic behavior of cis-[Pt(PEt3)2(neopentyl)Cl]Inorganic Chemistry, 1991
- Thermally reversible photoisomerization of a square-planar trans-diphosphinedichloropalladium(II) complex to yield its elusive cis-isomerJournal of the Chemical Society, Chemical Communications, 1979
- Isomerism energetics and mechanisms for palladium(II) phosphine complexes containing 5-methyl- and 5-trifluoromethyltetrazolesJournal of the American Chemical Society, 1974
- Mechanistic Studies of Isomerization Reactions of Tetragonal Planar Tertiary Phosphine Complexes of Palladium(II)Canadian Journal of Chemistry, 1973
- Organic syntheses by means of noble metal compounds. XXXIV. Carbonylation and decarbonylation reactions catalyzed by palladiumJournal of the American Chemical Society, 1968