Characterizing Oxidatively Damaged Cotton Fabrics

Abstract
"Catalytic damage" occurs in cotton fabrics during hydrogen peroxide bleaching. The model for catalytic damage proposed previously by Meyer, Kokot, Weber, and Zürcher is compared with a laboratory simulation of cotton cellulose damage produced using electrogenerated oxygen species at metal electrodes. Additional electrochemical information is provided to support the previously proposed mechanism of the damage of a cotton poplin. Diffuse reflectance infrared spectroscopy and chemometrics are used for relative qualitative and quantitative interpretation of the damage.

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