On the Thermal Dissociation of Organic Compounds. XV. Thermal Dissociation of Urethans in the Presence of Aromatic Amines
- 1 December 1960
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 33 (12) , 1707-1712
- https://doi.org/10.1246/bcsj.33.1707
Abstract
N-Phenyl phenylurethans dissociate readily into their component compounds in the presence of aliphatic amines and the plot for the second order reaction shows a straight line throughout a large portion of the dissociation. However, the rate of the dissociation of urethans in aromatic amines is much slower than in aliphatic ones and shows a tendency of increasing rate as the dissociation proceeds. The anomalous acceleration of the dissociation is due to the reaction products, urea and phenol.Keywords
This publication has 4 references indexed in Scilit:
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- On the Thermal Dissociation of Organic Compounds. X. The Effects of the Solvents (Amines and Fatty Acids) on the Thermal Dissociation of UrethansJournal of the American Chemical Society, 1956
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