Abstract
Urea derivatives of common isocyanates were formed with N-4-nitrobenzyl-N-n-propylamine (PNBPA) and chromatographed by reversed-phase liquid chromatography. Sample handling and the derivatization procedure were optimized with respect to simplicity, speed, and sensitivity. The resultant procedure is simple, reproducible, and reduces sample handling time from hours to as little as 15 minutes while maintaining detection limits for four common isocyanates below one ppb for a 20 liter air sample.

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