MEASUREMENT OF FORMAL POTENTIALS FOR HYPERICIN IN DIMETHYLSULFOXIDE

Abstract
The formal potentials for hypericin are measured in dimethylsulfoxide using cyclic voltammetry. Two reversible one‐electron reductions and a more poorly defined multielectron oxidation are observed. The formal potentials for these processes are consistent with the visible spectrum of hypericin and they indicated that hypericin is both a good oxidizing agent and a good reducing agent in the excited state.

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