The palladium catalysed carbonylation of nitrobenzene into phenyl isocyanate: a metallacyclic intermediate
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1616-1617
- https://doi.org/10.1039/c39900001616
Abstract
A metallacyclic complex has been isolated from the reaction of PhNO2 with CO using the Palladium(II)-o-phenanthroline system known to produce phenyl isocyanate or carbamates catalytically; reactions of this metallacycle have been studied and its rôle in the catalytic reaction discussed.Keywords
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