Visible absorption spectra of substituted ferricenium cations
- 1 January 1970
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 5,p. 280b-281
- https://doi.org/10.1039/c2970000280b
Abstract
The magnitude of the extinction coefficient and the shift on substitution show that the band at 16,200 cm–1 in the absorption spectrum of Fe(C5H5)2 +, which formerly was attributed to a 3d–3d ligand-field transition, is due to a ligand-to-metal e1u→e2g charge-transfer transition.Keywords
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