New Improved Reagents for the Asymmetric Allylation of Ketones
- 1 May 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (05) , 471-472
- https://doi.org/10.1055/s-1996-5450
Abstract
The synthesis of new 1,2-aminoalcohol derivatives 1b-d and 8a-h and their application in the stereoselective allylation of ethyl methyl ketones is described. The best results were obtained with the biphenyl derivative 8f, allowing the synthesis of tert-homoallylic ether 9f and 10f with a selectivity of 18:1.Keywords
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