The dipole-dipole potential in statistical mechanics
- 1 July 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 30 (1) , 31-36
- https://doi.org/10.1080/00268977500101731
Abstract
We study the interaction energy of a system of N particles with embedded point dipoles in a cube, this cube being duplicated indefinitely throughout space. We are able to evaluate exactly this energy for arbitrary positions and orientations of the N particles, to provide an effective hamiltonian suitable for the study of the statistical mechanics of dipolar systems by both rigorous methods and computer simulation techniques. We describe methods for the rapid numerical evaluation of the hamiltonian and how it may be employed for the tasks outlined above.Keywords
This publication has 23 references indexed in Scilit:
- Perturbation theory for the angular correlation functionMolecular Physics, 1974
- Application of thermodynamic perturbation theory to polar and polarizable fluidsJournal of Physics C: Solid State Physics, 1974
- Dielectric properties of a model fluid with the Monte Carlo methodChemical Physics, 1974
- Theory of polar liquidsMolecular Physics, 1973
- The free energy of spheres with dipoles: Monte Carlo with multistage samplingChemical Physics Letters, 1973
- Mean Spherical Model Integral Equation for Charged Hard Spheres I. Method of SolutionThe Journal of Chemical Physics, 1972
- Exact Solution of the Mean Spherical Model for Fluids of Hard Spheres with Permanent Electric Dipole MomentsThe Journal of Chemical Physics, 1971
- Mode Expansion in Equilibrium Statistical Mechanics. II. A Rapidly Convergent Theory of Ionic SolutionsThe Journal of Chemical Physics, 1971
- Monte Carlo Study of the Thermodynamics of Electrolyte SolutionsThe Journal of Chemical Physics, 1970
- Integral Equation Computations for Aqueous 1–1 Electrolytes. Accuracy of the MethodThe Journal of Chemical Physics, 1969