Carbon and oxygen isotopic composition of structural carbonate in sedimentary francolite

Abstract
δ 13 C values for carbonate in francolite clearly distinguishes between authigenic varieties precipitated within anoxic sediments and diagenetic varieties produced by phosphatization of carbonates. δ 18 O values are characteristic of a deposit and, whilst apparently in equilibrium with pore-water in Recent deposits, are probably unreliable as palaeotemperature indicators generally. The isotopic composition of carbonate may therefore be used as a pointer to the mechanism of origin of francolite.