Novel molecular structures of (Ph3P)4(AgSBut)14, a convoluted 28-membered monocycle, and (Ph3P)2(AgSCMeEt2)8
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 17-18
- https://doi.org/10.1039/c39840000017
Abstract
(Ph3P)4(AgSBut)14, virtual symmetry C2h, contains a 28-membered cycle of alternating sulphur and silver atoms with phosphine ligands at Ag-(1),-(6),-(8),-(13), folded without contracycle connections into an orthorhombic molecular box, while (Ph3P)2(AgSCMeEt2)8 contains weakly connected Ag4(SR)4 and (Ph3P)2Ag4(SR)4 cycles.Keywords
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