The asymptotic dispersion of particles in N-layer systems: Periodic boundary conditions
- 1 January 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 86 (1) , 454-459
- https://doi.org/10.1063/1.452585
Abstract
Previous work on dispersion of particles in N‐layer systems (generalized Taylor dispersion) for reflecting boundaries is extended to the case of periodic boundary conditions. An explicit expression for the dispersion is presented; this is never greater than the dispersion for the corresponding system with reflecting boundaries. Applications to chromatography with chemical reaction and to anomalous diffusion are made.Keywords
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