Bis(η-cyclopentadienyl)imidomolybdenum compounds
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 155-162
- https://doi.org/10.1039/dt9950000155
Abstract
The mono(η-cyclopentadienyl)imide compounds [Mo(η-C5H4R)(NR′)Cl2](R, R′= H, R″; Me, Pri; Me, R″; or Pri, R″; R″= C6H3Me2-2,6) and the new bis(η-cyclopentadienyl)imide compounds [Mo(η-C5H4R)2(NR′)](R, R′= Me, But; H, But; H, Pri; H, Ph; H, R″; Me, Pri; Me, Ph; Me, R″; Pri, But; or Pri, R″), [Mo(η-C5H5)(η-C5H4Pri)(NBut)], [Mo(η3-C9H7)(η-C5H4Pri)(NBut)] and [Mo(η- C5H4Me)2Me(NBut)]X (X = I or BF4) have been prepared. The salt [Mo(η-C5H4Me)(PMe3)2(NBut)][C5H4Me] has also been prepared. The crystal structures of the latter and of [Mo(η-C5H5)2(NBut)] have been determined.Keywords
This publication has 1 reference indexed in Scilit:
- tert-Butylimino-cyclopentadienyIvanadiuni(V)-Verbindungen Darstellung, Struktur und NMR-spektroskopische UntersuchungenZeitschrift für Naturforschung B, 1987