Control of addition: reduction ratio in the Grignard reaction with ketones by a salt effect
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 8,p. 470-471
- https://doi.org/10.1039/c29700000470
Abstract
The yield of addition of a Grignard reagent to a hindered ketone has been enhanced at the expense of reduction by complexing the Grignard reagent with lithium perchlorate or tetrabutylammonium bromide.Keywords
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