Total synthesis of oestra-1,3,5(10)-trien-17-one

1 January 1979

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 24,p. 1119-1120
https://doi.org/10.1039/c39790001119

Abstract

A highly efficient and stereoselective synthesis of oestra-1,3,5(10)-trien-17-one (1) from the sulphones (8)via intramolecular capture of o-quinodimethanes generated by cheletropic elimination of SO₂ is reported.

Keywords

TOTAL SYNTHESIS
OESTRA
TRIEN
STEREOSELECTIVE SYNTHESIS
INTRAMOLECULAR CAPTURE
CHELETROPIC ELIMINATION
QUINODIMETHANES GENERATED
HIGHLY EFFICIENT
SO2

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