Ion neutralization reactions in irradiated hydrogen chloride, hydrogen bromide, and nitrous oxide

Abstract
Rates of ion neutralization have been measured in hydrogen chloride, hydrogen bromide, and nitrous oxide by collecting the ions remaining in a defined volume at various times after ionization by a pulse of 120 k.v.p. X-rays. Values of the total homogeneous ion-ion recombination coefficient, a, have been obtained for each gas over a range of pressures in the region 50 to 650 Torr. From a study of the effects of pressure and ion density, the relative rates of wall diffusion, mutual neutralization, and three-body neutralization have been deduced.

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