Magnetic circular dichroism spectroscopy of matrix-isolated species
- 1 December 1974
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 28 (6) , 1377-1388
- https://doi.org/10.1080/00268977400102661
Abstract
An apparatus is described for measuring the magnetic circular dichroism spectra of matrix-isolated species over the temperature range 14–50 K. Results are presented illustrating the range of materials which can be investigated (from mercury atoms to phthalocyanine molecules). The detection of transitions in oxygen, which are extremely weak in absorption, clearly demonstrates the high sensitivity of magnetic circular dichroism measurements on paramagnetic species at low temperature.Keywords
This publication has 12 references indexed in Scilit:
- Detection and assignment of weak absorption bands by magnetic circular dichroism: Spin-forbidden transitions of CoCl42−Chemical Physics Letters, 1971
- The Faraday effectQuarterly Reviews, Chemical Society, 1969
- Charge-Transfer Spectra of Matrix-Isolated 3d Transition-Metal DichloridesThe Journal of Chemical Physics, 1968
- Spectra of porphyrinsJournal of Molecular Spectroscopy, 1968
- ESR of Cu(NO3)2 and CuF2 Molecules Oriented in Neon and Argon Matrices at 4°KThe Journal of Chemical Physics, 1966
- Ultraviolet Absorption Spectrum of Mercury in Low-Temperature MatricesThe Journal of Chemical Physics, 1965
- FORBIDDEN TRANSITIONS IN DIATOMIC MOLECULES: III. NEW AND ABSORPTION BANDS OF THE OXYGEN MOLECULECanadian Journal of Physics, 1953
- FORBIDDEN TRANSITIONS IN DIATOMIC MOLECULES: II. THE ABSORPTION BANDS OF THE OXYGEN MOLECULECanadian Journal of Physics, 1952
- Über die Deutung der O4-Spektren und die Existenz mehratomiger PolarisationsmoleküleThe European Physical Journal A, 1934
- Über die Absorptionsspektren des hochkomprimierten Sauerstoffs und die Existenz von O4-MolekülenThe European Physical Journal A, 1932