Enantioselective Synthesis of the Cyclopentene Segment of Queuosine

1 February 1996

journal article
research article
Published by Georg Thieme Verlag KG in Synthesis

Vol. 1996 (02) , 219-222
https://doi.org/10.1055/s-1996-4197

Abstract

(3S,4R,5S)-3-Amino-4,5-dihydroxycyclopentene, the cyclopentene segment of queuosine found in the first position of the anticodon of +RNA,^Tyr+RNA,^His+RNA,^Asn and +RNA,^Asp has been synthesized in a stereoselective manner from (-)-3-endo-hydroxydicyclopentadiene.

Keywords

QUEUOSINE
(3S
5S)-3-AMINO-4
5-DIHYDROXYCYCLOPENTENE
ENANTIOSELECTIVE SYNTHESIS
CHIRAL CYCLOPENTADIENOL SYNTHON
CHIRAL ENDO-3-HYDROXYDICYCLOPENTADIENE

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