Free radical brominative ring opening of 1,2-O-benzylidene pyranoses: a route to glycosylating agents
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 272-274
- https://doi.org/10.1039/c39880000272
Abstract
Bromination of fully protected 1,2-O-benzylidenated pyranoses with bromotrichloromethane and u.v. light or N-bromosuccinimide gives 2-O-benzoyl glycosyl bromides in good yields, which may be converted in situ to glycosides and disaccharides.Keywords
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