Surface dimerization induced CuPtB versus CuPtA ordering of GaInP alloys

Abstract
Using a valence force field approach and ab initio pseudopotential calculations, we examine the role of subsurface strain in the ordering of Ga0.5In0.5P alloys. We show that depending on the orientation of the surface phosphorus dimers, these alloys can have (i) a CuPtA ordering for 1×2 or c(4×4) reconstruction; (ii) a CuPtB ordering for 2×1 or β2(2×4) reconstruction; and (iii) a triple period ordering for 2×3 or c(8×6) reconstruction. These results are in good agreement with recent experiments of Gomyo et al. [Phys. Rev. Lett. 72, 673 (1994); Jpn. J. Appl. Phys. 34, L469 (1995)].