A Microporous Lanthanide-Organic Framework
- 3 September 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (17) , 2590-2594
- https://doi.org/10.1002/(sici)1521-3773(19990903)38:17<2590::aid-anie2590>3.0.co;2-h
Abstract
Stable zeolite‐like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide–benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of TbIII and 1,4‐benzenedicarboxylic acid. The open Tb–BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.Keywords
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