Kinetic evidence for a six-co-ordinate silicon intermediate in the racemisation of chlorosilanes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1086-1087
- https://doi.org/10.1039/c29710001086
Abstract
A kinetic study of the racemisation of chlorosilanes shows that the racemisation is second-order with respect to reagent; thus the intermediate is probably octahedral, with each molecule of chlorosilane co-ordinated by two molecules of reagent.Keywords
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