Planar Chiral Arylaldehydeimine Tricarbonylchromium Complexes in the Asymmetric Baylis - Hillman Coupling Reaction

1 January 1994

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1994 (06) , 413-414
https://doi.org/10.1055/s-1994-22869

Abstract

The DABCO-catalyzed coupling reaction of methyl acrylate and acrylonitrile with enantiomerically pure planar chiral o-substituted (benzaldehyde tosylimine) Cr(CO)₃ complexes after metal removal provides chiral amines in high yields and enantiomeric excess.

Keywords

CHIRAL
PLANAR
DABCO
TRICARBONYLCHROMIUM
REMOVAL
AMINES
BAYLIS
TOSYLIMINE

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