New mixed-metal clusters via metal hydride coupling. Synthesis and crystal structures of [(µ2-H)Os3W(CO)12(η5-C5H5)] and [(µ2-H)3Os3W(CO)11(η5-C5H5)]
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 534-535
- https://doi.org/10.1039/c39780000534
Abstract
The reaction of [Os3(CO)10(NCMe)2] with the hydrido-complex [HW(CO)3(η5-C5H5)] under mild conditions yields the heteronuclear metal carbonyl hydride complexes [(µ2-H)Os3W(CO)12(η5-C5H5)](1) and [(µ2-H)3Os3W(CO)11(η5-C5H5)](2); the complexes have been characterized by X-ray diffraction studies and the locations of the bridging hydride ligands have been ascertained.Keywords
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