The Structure of Derivatives of [SCH3Fe(CO)3]2

Publisher Website
Google Scholar
Abstract
[SCH3Fe(CO)3]2 when separated into its two known isomers reacts with tertiary phosphines with retention of the sulfur-methyl group configuration. The reaction of the mixture of isomers of [SCH3-Fe(CO)3]2 with ditertiary phosphines and arsines has been studied. Some ligands give bridged complexes and others chelates: one ligand gives both. The p.m.r. and Mössbauer spectra of these complexes are discussed.

This publication has 0 references indexed in Scilit: