Reversible Migratory Insertion/β-Alkyl Elimination in α-Agostic Alkylniobium Alkyne Complexes

This publication has 53 references indexed in Scilit:

• Homoscorpionate (Tris(pyrazolyl)borate) Ligands Containing Tethered 3-Phenyl Groups
  Inorganic Chemistry, 1994
• Why Is .beta.-Me Elimination Only Observed in d0 Early-Transition-Metal Complexes? An Organometallic Hyperconjugation Effect with Consequences for the Termination Step in Ziegler-Natta Catalysis
  Organometallics, 1994
• Organometallic diazo compounds
  Chemical Reviews, 1993
• N-Halogenoimido complexes of transition metals
  Chemical Reviews, 1993
• Carbon-carbon activation at electrophilic d0/fn centers. Facile, regioselective .beta.-alkyl shift-based ring-opening polymerization reactions of methylenecyclobutane
  Journal of the American Chemical Society, 1993
• Synthesis and structure of moderately stable metallaoxetanes: [cyclic](.eta.5-C5Me5)2(CH3)TaOCHRCH2 (R = H, C6H5). Investigations of their decomposition to olefin and (.eta.5-C5Me5)2Ta(:O)CH3 and evidence revealing that they are not intermediates in the deoxygenation of epoxides by [(.eta.5-C5Me5)2Ta(CH3)]
  Journal of the American Chemical Society, 1991
• Evidence for carbon–hydrogen–titanium interactions: synthesis and crystal structures of the agostic alkyls [TiCl₃(Me₂PCH₂CH₂PMe₂)R](R = Et or Me)
  J. Chem. Soc., Dalton Trans., 1986
• Nucleophilic addition reactions with iron .eta.2-alkyne derivatives. Synthesis and investigation of CpFeCO(L)(.eta.1-alkenyl) [L = PPh3, P(OPh)3] complexes
  Organometallics, 1984
• Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenylphosphine)nickel. A cis insertion that leads to trans kinetic products
  Journal of the American Chemical Society, 1981
• The preparation, structures and reactivity of complexes with molybdenum-nitrogen multiple bonds
  Journal of the Less Common Metals, 1977