Pyrolysis of Acid Amides. III. Pyrolysis of Cyanoacetamides and 2-Phenylacetamides
- 1 January 1963
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 36 (1) , 95-99
- https://doi.org/10.1246/bcsj.36.95
Abstract
The pyrolyses of cyanoacetamides, 2-phenylacetanilide, 2,2-diphenylacetanilide and 2,2,2-triphenylacetanilide have been studied. The pyrolysis of cyanoacetamides gave the corresponding isocyanates and acetonitrile. On the other hand, the pyrolysis of 2-phenylacetanilide and 2,2-diphenylacetanilide gave a small amount of phenyl isocyanate, along with various byproducts. The pyrolysis of 2,2,2-triphenyl-acetanilide, however, against expectation, did not give isocyanate; only a tarry product resulted.Keywords
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