Chemical Evolution of Damped Ly alpha galaxies: The [S/Zn] abundance ratio at redshift z > 2

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Abstract
Relative elemental abundances, and in particular the alpha/Fe ratio, are an important diagnostic tool of the chemical evolution of damped Ly alpha systems (DLAs). The S/Zn ratio is not affected by differential dust depletion and is an excellent estimator of the alpha/Fe ratio. We report 6 new determinations of sulphur abundance in DLAs at zabs greater than or equal to 2 with already known zinc abundances. The combination with extant data from the literature provides a measure of the S/Zn abundance ratio for a total of 11 high redshift DLA systems. The observed [S/Zn] ratios do not show the characteristic [alpha/Fe] enhancement observed in metal-poor stars of the Milky Way at comparable level of metallicity ([Zn/H] ~ -1). The behaviour of DLAs data is consistent with a general trend of decreasing [S/Zn] ratio with increasing metallicity [Zn/H]. This would be the first evidence of the expected decrease of the alpha/Fe ratio in the course of chemical evolution of DLA systems. However, in contrast to what observed in our Galaxy, the alpha/iron-peak ratio seems to attain solar values when the metallicity is still low ([Zn/H] < -1) and to decrease below solar values at higher metallicities. The behaviour of the alpha/Fe ratio challenges the frequently adopted hypothesis that high redshift DLAs are progenitors of spiral galaxies and favours instead an origin in galaxies characterized by low star formation rates, in agreement with the results from imaging studies of low redshift DLAs, where the candidate DLA galaxies show a variety of morphological types including dwarfs and LSBs and only a minority of spirals.

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