Die Mikrobestimmung der Barbiturate. Ein neues mikrotechnisches Arbeitsverfahren

Abstract
A method is described for the estimation of 10-70 [mu]g of barbiturates present on filter paper. It is therefore suitable for estimation of barbiturates after paper chromatography. The spot with the substance is wetted with Hg reagent, excess reagent removed by 2 rapid washings of 5 ml on the pump, and the Hg bound in the complex is then estimated by means of dithizone at 610 m[mu] Calibration curves are presented for luminal, veronal and phanodorm. It is considered that the method can be adapted for estimation of less than 1 [mu]g barbiturate.

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