ELECTRONIC STATES OF HYDRATED VANADIUM (II) ION
- 1 December 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (12) , 2319-2323
- https://doi.org/10.1139/v60-314
Abstract
The optical absorption of a single crystal of VSO4.7H2O was measured in the range 9000–35,000 cm−1. The three observed bands were assigned to transitions between the four orbital levels resulting from cubic electrostatic perturbation of the spherical terms of configuration 3d3. Values of Dq = 1200 cm−1 and E = 10,000 cm−1 were derived from the spectral analysis.Keywords
This publication has 7 references indexed in Scilit:
- Intensities in inorganic complexesMolecular Physics, 1959
- The distribution of transition metal cations in spinelsJournal of Physics and Chemistry of Solids, 1957
- On the stabilities of transition metal complexes—I Theory of the energiesJournal of Inorganic and Nuclear Chemistry, 1956
- Spectra of Transition-Metal ComplexesThe Journal of Chemical Physics, 1955
- On the Absorption Spectra of Complex Ions. IJournal of the Physics Society Japan, 1954
- Electrochemical Studies on Vanadium Salts. I. The Vanadyl-Vanadic Oxidation-Reduction Potential1Journal of the American Chemical Society, 1944
- On the Energy Levels of Chrome AlumThe Journal of Chemical Physics, 1940