Synthetic Applications of Double Functionalization by Cooperating Sulfur- and Oxygen-Containing Substituents
- 1 January 1988
- journal article
- review article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1988 (02) , 95-102
- https://doi.org/10.1055/s-1988-27479
Abstract
This review describes the cooperating effect of unsymmetrical disubstitution by sulfur- and oxygen-containing functional groups which gives rise to unique reactivities and synthetic utilities. 1. Introduction 2. Geminal Disubstitution 2.1. Novel One-Carbon Homologation Reagents 2.2. α-Acetoxy Ethers 2.3. Other Syntheses Following the One-Carbon Homologation 3. Vicinal Disubstitution 4. Allylic Disubstitution 5. Concluding RemarksKeywords
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