‘Bis(triphenylphosphine)palladium:’ its generation, characterization, and reactions
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1338-1339
- https://doi.org/10.1039/c39860001338
Abstract
Pd0–PPh3 complexes obtained by reduction of X2Pd(PPh3)2, where X is Cl, Br, or I, with various reducing agents, e.g., RLi and Bui 2AlH, are neither free Pd(PPh3)2 nor its polymer, those derived from RLi being consistent only with LiXPd(PPh3)2, Li2X2Pd(PPh3)2, and aggregates thereof.Keywords
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