Palladium-catalysed intramolecular asymmetric ene reaction of chiral allylic sulphones via chiral allylic sulphinate–sulphone rearrangements
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1778-1780
- https://doi.org/10.1039/c39890001778
Abstract
The chirality of the sulphinate sulphur atoms has been transferred to the carbon centres in chiral allylic sulphinate–sulphone rearrangements, followed by palladium-catalysed intramolecular ene reactions of the chiral allylic sulphones obtained, with high stereospecificity.Keywords
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